AFAIK, the only real way to easily ID whether it is the gun or ammo is to try another one and see what happens. Obviously if it happens in the 13.7 with the same ammo, it’s ammo related. My Criterion barrel popped MEN primers the vast majority of the time, but it did pop an Igman .223 once or twice as well. I’ve also run the MEN is a number of other uppers without issue, so pretty easy to say that it was something wrong with the gun.
While that’s all fairly obvious, I’m not aware of anyone that considers blown primers a symptom of simple overgassing. Common overgassing is just excessive felt recoil and fouling. Excessive overgassing leads the bolt to out-running the magazine, causing malfunctions. Overgassing can be solved a few ways, my preferred would be a BRT gas tube and/or LMT E-carrier before anything adjustable.
Blown primers are the next step up and a over-pressurization issue. If it can be identified as the upper, it needs to go back to the manufacturer to probably get the barrel replaced.
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